Multi-stage drilling waste material recovery process

ABSTRACT

A process for removing free liquids from oil base mud contaminated drill cuttings waste. A process is described wherein a high gravity centripetal separator and low temperature thermal process are cooperatively used to enhance the mechanical and thermal separation methods, resulting in improved efficiency of the hydrocarbon and water removal process. A process is also described wherein the oil base mud contaminated drill cuttings waste is heated to strip volatile constituents and excess water from the oil base mud contaminated drill cuttings to further enhance the mechanical and thermal separation methods resulting in improved efficiency of the hydrocarbon and water removal process. A less expensive process is also described where the oil base mud contaminated drill cuttings waste is heated to strip volatile constituents and excess water from the oil base mud contaminated drill cuttings to further enhance the recoverable liquids phase during mechanical separation. A conventional stripping process for oil base mud is also utilized.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit under 35 U.S.C. §119(e) of U.S.Provisional Application Ser. No. 62/324,622 filed Apr. 19, 2016, thedisclosure of which is expressly incorporated by reference herein in itsentirety.

TECHNICAL FIELD

The field of art to which this invention generally pertains is theprocessing of drill cuttings waste.

BACKGROUND

During the drilling of a well, gas or oil for example, drilling mud istypically pumped down the drill string through a drill bit. The drillingmud simultaneously cools the bit and carries drill cuttings up the wellbore. Drilling mud is typically comprised of a fluid (or fluids), andmixture of additives which can be either fluids or solids, forming auseable drilling fluid. Oil based or brine based drilling fluids areoften used to drill oil and gas wells because they have specialcharacteristics that make them a better cooling/carrying fluid thanother drilling muds. Additionally, such drilling muds may offer betterwellbore stability and/or lubricity for the drill string in modern,horizontal wellbores.

Typically, the drill cuttings which are carried up the wellbore aresubjected to solids separating devices when the cuttings exit thewellbore, such as that of shale shakers or decanter centrifuges. Thesemechanical separators allow a substantial portion of the drilling mud tobe returned to the storage tanks for reuse, while the drill cuttingsportion is sent to separate storage tanks. The drill cuttings stillcontain residual amounts of the drilling mud that couldn't be separatedthrough mechanical means, and this residual drilling mud is consideredto be contamination.

The drill cuttings are commonly known as drilling waste, because theyserve no purpose after they have been removed from the wellbore. Thus,the contaminated drill cuttings are typically stabilized with a bulkingagent, such as fly-ash, sawdust, or liquid absorbing pellets, to preventresidual free liquids from leaching from the solids during transport.The cuttings are then typically transported to a secure landfill wherethey are stored for an indeterminate period of time, typicallygenerations.

With the evolution of new technologies such as thermal extraction,solvent washes, mechanical separators, and the increasing cost ofdrilling fluids, the ability to, and benefits of, reclaiming materialsfrom the drill cuttings waste, such as various components of thedrilling fluids, is increasing.

Accordingly, there is a constant search for new technologies andimprovements to existing technologies to increase the efficiency andeffectiveness of reclaiming processes.

BRIEF SUMMARY

A process for removing hydrocarbon and water contamination from a firstphase oil base mud contaminated drill cuttings containing liquids andsolids, and recovering liquids in a multi-stage separation process isdescribed, including placing the first phase oil base mud contaminateddrill cuttings in a container and managing the flow of the first phaseoil base mud contaminated drill cuttings into and out of the containerto a substantially consistent ratio of liquids phase to solids phase;conveying the first phase oil base mud drill cuttings into a highgravity centripetal cuttings separator to create a second solids phasewith less water and hydrocarbon contamination and a third liquids phasewith an approximately equal ratio of liquids to solids; conveying thesaid third liquids phase with an approximately equal ratio of liquids tosolids into a low temperature thermal process utilizing stationaryreactor walls and high speed rotating paddles, the solids in the thirdphase causing friction between the stationary reactor walls and highspeed rotating paddles of the low temperature thermal process, and thefriction generating heat energy causing evaporation of the liquidsportion of the third phase into a fourth vapor phase and a sixth solidsphase; condensing the fourth vapor phase into a fifth liquid phasecomprising water and/or hydrocarbons, and collecting the fifth liquidphase; and mixing the sixth solids phase with the second solids phase toform a seventh mixed solids phase; resulting in enhanced liquids andsolids recovery.

Additional embodiments include: the process described above where thehigh gravity centripetal cuttings separator exerts greater than 400gravitational forces on the oil base mud contaminated drill cuttingswaste; the process described above where the high gravity centripetalcuttings separator exerts greater than 1000 gravitational forces on theoil base mud contaminated drill cuttings waste; the process describedabove where the high gravity centripetal cuttings separator is operatedto obtain maximum dryness of the second solids phase; the processdescribed above where the first phase oil base mud contaminated drillcuttings is heated to a temperature of at least 20° C. at 0 PSIG (poundsper square inch gravity); the process described above where the heatingis provided by natural gas or recycled heat energy from the condensingof the fourth vapor phase; the process described above where thecentripetal cuttings separator removes greater than 50% by volume of theliquids phase from the first oil base mud contaminated drill cuttingsphase; the process described above where the liquids phase comprises atleast free water, hydrocarbons, and/or emulsified water; the processdescribed above where the enhanced liquids and solids recovery includesan increase of drill cuttings waste throughput of the low temperaturethermal process by greater than 25% and/or cleaner solids recovery; theprocess described above where the enhanced liquids and solids recoveryincludes an increase of drill cuttings waste throughput of the lowtemperature thermal process by greater than 50% and/or cleaner solidsrecovery containing less hydrocarbon contamination; and the processdescribed above where the enhanced liquids and solids recovery includesan increase of drill cuttings waste throughput of the low temperaturethermal process by up to 100% and/or cleaner solids recovery.

A process for removing hydrocarbons and water from a first phase oilbase mud contaminated drill cuttings and recovering liquids in amulti-stage separation process is also described, including heating thefirst phase oil base mud contaminated drill cuttings to remove at leasta portion of undesired liquid constituents as a ninth vapor phase andrecondensing the ninth vapor phase in an operatively connected condenserthereby forming a twelfth liquids phase, and forming a heated eightphase oil base mud contaminated drill cuttings containing a liquidsportion and a solids portion; conveying the heated eight phase of oilbase mud contaminated drill cuttings into a high gravity centripetalcuttings separator to create a second solids phase containing less waterand hydrocarbons contamination than the eight phase, and a third liquidsphase with less solids than the eight phase; conveying the third liquidsphase to a fluid stripping process removing low gravity solids,producing a thirteenth phase of low gravity solids with reduced liquidsand a tenth liquids phase with substantially no solids; conveying thesecond solids phase and thirteenth low gravity solids phase to a lowtemperature thermal process utilizing stationary reactor walls and highspeed rotating paddles, the interaction between the solids of the secondand thirteenth phase and the stationary reactor walls and high speedrotating paddles generating at least a portion of the heat energynecessary to cause evaporation of the liquids of the second andthirteenth phase into a fourth vapor phase; condensing the fourth vaporphase into a fifth liquid phase comprising water and/or hydrocarbons,and collecting the fifth liquid phase; and collecting the tenth liquidsphase from the fluid stripping process which is optionally stored in astorage tank or mixed with the fifth liquids phase to create a eleventhliquids phase for use in an oil base mud drilling fluid; resulting inenhanced liquids and solids recovery.

Additional embodiments include: the process described above where theninth phase of undesired liquid constituents removed comprise at least aportion of water, and/or at least a portion of benzene, and/or at leasta portion of toluene, and/or at least a portion of ethylbenzene, and/orat least a portion of xylene from the first phase; the process describedabove where the undesired liquid constituents removed include liquidswith a closed cup flash point of less than 60° C.; the process describedabove where the undesired liquid constituent removed includes a gas orliquid containing fewer than nine carbon atoms per molecule; the processdescribed above where the viscosity of the liquids portion of the eightphase is less than 1.0 cP (centipoise) as a result of the said heating;the process described above where the viscosity of the liquids portionof the eight phase is less than 0.75 cP as a result of the said heating;the process described above where the high gravity centripetal cuttingsseparator exerts greater than 400 gravitational forces on the oil basemud contaminated drill cuttings; the process described above where thehigh gravity centripetal cuttings separator exerts greater than 1000gravitational forces on the oil base mud contaminated drill cuttings;the process described above where the high gravity centripetal cuttingsseparator is operated to achieve a minimum amount of solids in the thirdliquids phase; the process described above where the heating of thefirst phase of oil base mud contaminated drill cuttings includes the useof a holo-flight heating screw; the process described above where theheating of the first phase of oil base mud contaminated drill cuttingsincludes the use of a conveyor within a jacketed heating trough; theprocess described above where the heating of the first phase of oil basemud contaminated drill cuttings includes the use of a tank filled withhot oil containing 10 to 30 carbon atoms per molecule; the processdescribed above where the heating of the first phase of oil base mudcontaminated drill cuttings includes the use of a tank filled with hotoil containing 10 to 25 carbon atoms per molecule; the process describedabove where the heating of the first phase of oil base mud contaminateddrill cuttings includes the use of a tank filled with hot oil containing11 to 20 carbon atoms per molecule; the process described above wherethe enhanced liquids and solids recovery includes an increase of drillcuttings waste throughput of the low temperature thermal process bygreater than 25% and/or cleaner solids recovery; the process describedabove where the enhanced liquids and solids recovery includes anincrease of drill cuttings waste throughput of the low temperaturethermal process by greater than 50% and/or cleaner solids recovery; theprocess described above where the enhanced liquids and solids recoveryincludes an increase of drill cuttings waste throughput of the lowtemperature thermal process by up to 100% and/or cleaner solidsrecovery; and the process described above where the heating of the firstphase of oil base mud contaminated drill cuttings is provided by naturalgas and/or recycled heat energy from the low temperature thermalprocess.

A method of treating a first phase oil base mud contaminated drillcuttings phase is also described including heating the first phase oilbase mud contaminated drill cuttings in a heating tank and causingconstituents with a lower boiling point than the boiling points of thebase oil portion of the oil base mud, to at least partially vaporize andleave the vapor tight heating tank as a ninth vapor phase where thevapors are recondensed in an operatively connected condenser andcollected as a separate twelfth liquids phase, and further processingthe eight phase of oil base mud contaminated drill cuttings phase in acentripetal cuttings separator to create a liquids phase containing lesssolids than the first phase oil base mud contaminated drill cuttings,and a solids phase containing less liquids than the first phase oil basemud contaminated drill cuttings, resulting in enhanced liquids which areat least partially void of water, benzene, toluene, ethylbenzene andxylene and constituents containing fewer than nine carbon atoms permolecule.

These, and additional embodiments, will be apparent from the followingdescriptions.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 demonstrates an embodiment of how a typical drilling rig managesfluids and solids operations onsite.

FIG. 2 is a picture of unstabilized drill cuttings, stabilizing (orbulking) agent, and stabilized drill cuttings (ready for storage in alandfill) respectively.

The FIG. 3 shows a flow chart of an embodiment of the methods describedherein. Specifically, the use of a high gravity centripetal separator toremove free liquids prior to employing the use of a Low TemperatureThermal processor to clean the drill cuttings waste, with greaterefficiency.

FIG. 4 shows a flow chart of an embodiment of the methods describedherein. Specifically, by adding less expensive heat energy to the liquidcontaining drill cuttings in an effort to cause at least a portion ofthe liquids phase to evaporate prior to employing the use of a highgravity centripetal separator to remove additional free liquids.Thereafter, the flow chart illustrates the use of a Low TemperatureThermal processor to treat the concentrated liquids phase and solidsphase recovered from the high gravity centripetal separator.

FIG. 5 shows a flow chart of an embodiment of the methods describedherein. Specifically, by adding less expensive heat energy to the liquidcontaining drill cuttings in an effort to cause at least a portion ofthe liquids phase to evaporate, prior to employing the use of a highgravity centripetal separator to remove additional free liquids. This isa very low cost method of recovering an enhanced liquids phase.

FIG. 6 is a table to illustrate the change in viscosity of diesel fuelas the temperature rises from cooler to hotter.

FIG. 7 illustrates the normal boiling point range of carbon fractions,and various hydrocarbon fuels, their carbon fraction makeup, and thesame for synthetic and distillate base oils, used to blend oil base mud.

DETAILED DESCRIPTION

The particulars shown herein are by way of example and for purposes ofillustrative discussion of the various embodiments of the presentinvention only and are presented in the cause of providing what isbelieved to be the most useful and readily understood description of theprinciples and conceptual aspects of the invention. In this regard, noattempt is made to show details of the invention in more detail than isnecessary for a fundamental understanding of the invention, thedescription making apparent to those skilled in the art how the severalforms of the invention may be embodied in practice.

The present invention will now be described by reference to moredetailed embodiments. This invention may, however, be embodied indifferent forms and should not be construed as limited to theembodiments set forth herein. Rather, these embodiments are provided sothat this disclosure will be thorough and complete, and will fullyconvey the scope of the invention to those skilled in the art.

Unless otherwise defined, all technical and scientific terms used hereinhave the same meaning as commonly understood by one of ordinary skill inthe art to which this invention belongs. The terminology used in thedescription of the invention herein is for describing particularembodiments only and is not intended to be limiting of the invention. Asused in the description of the invention and the appended claims, thesingular forms “a,” “an,” and “the” are intended to include the pluralforms as well, unless the context clearly indicates otherwise. Allpublications, patent applications, patents, and other referencesmentioned herein are expressly incorporated by reference in theirentirety.

Unless otherwise indicated, all numbers expressing quantities ofingredients, reaction conditions, and so forth used in the specificationand claims are to be understood as being modified in all instances bythe term “about.” Accordingly, unless indicated to the contrary, thenumerical parameters set forth in the following specification andattached claims are approximations that may vary depending upon thedesired properties sought to be obtained by the present invention. Atthe very least, and not as an attempt to limit the application of thedoctrine of equivalents to the scope of the claims, each numericalparameter should be construed in light of the number of significantdigits and ordinary rounding approaches.

Notwithstanding that the numerical ranges and parameters setting forththe broad scope of the invention are approximations, the numericalvalues set forth in the specific examples are reported as precisely aspossible. Any numerical value, however, inherently contains certainerrors necessarily resulting from the standard deviation found in theirrespective testing measurements. Every numerical range given throughoutthis specification will include every narrower numerical range thatfalls within such broader numerical range, as if such narrower numericalranges were all expressly written herein.

The following terminology is included for ease of understanding of thereader:

Drilling fluid—used in the drilling industry to carry the drillcuttings/solids phase (rock, clay, shale, etc.) broken up by the drillbit out of the well bore. Drilling fluid (also known as drilling mud)consists of a base fluid with additives which can include liquids orsolids or both, which give the drilling fluid properties necessary foreffective use as a drilling mud.

Oil based mud—(OBM) also known as Invert, is a type of drilling fluidthat uses oil as the base ingredient and it typically consists of amixture of oil, emulsified water and drilling mud additives which mightbe solids or liquids or both. OBM's typically consist of distillates orsynthetic oil as the base fluid. Conversely, water based mud is adrilling fluid that uses water as the base ingredient, mixed withliquids or solids or both. Common types of water base muds are gel-chemmud systems, brine mud systems or polymer mud systems.

Low Gravity Solids—(LGS) are typically less than 20 microns in size andconsist of drilling mud additives or formation solids. Formation solidsbegin as larger drill cutting pieces for example, as large as 2centimeters in diameter, of which a portion of the larger pieces becomebroken or ground down to less than 20 microns by the time they arrive atsurface.

Viscosity is best understood as the thickness of a fluid. For example,water has relatively low viscosity, whereas a milkshake has a higherviscosity.

Rheology is the science of explaining liquid flow. One of the importantrheology properties of drilling mud is the ‘yield point’, or thecarrying capacity of the fluid. A small solid dropped in a glass ofwater demonstrates a fluid with no yield point, because the small solidwill drop regardless of its size. The same size solid in a milkshake maynot drop at all because the force of gravity may not be strong enough tobreak the yield point of the milk shake. If it is heavy enough to exceedthe yield point of the fluid it will drop more slowly than the same sizesolid in water due to the higher viscosity of the milk shake. Drillingmud is typically modeled as a Bingham plastic. Bingham Plastics areliquids that behave like a solid, up to a particular amount of shearstress, when they behave more like a liquid than a solid; this is knownas the yield point of the fluid.

The temperatures referenced herein are at 0 PSIG. If one decides to usepressures above or below 0 PSIG, one would know to, and would adjust thetemperatures, accordingly, to obtain the similar and desired resultsdescribed herein.

With the significant cost of drilling muds, there has been research anddevelopment to most effectively recover as much of the drilling mud aspossible, by using solids separating devices or fluids rehabilitationdevices. Such systems include shale shakers, centrifuges, centripetaldryers, thermal extraction systems or diluent washing systems.

Typically, the drill cuttings are carried up the wellbore by thedrilling mud and passed over a shale shaker(s) to remove a substantialportion of the drilling mud. Shale shakers are considered the first lineof defense on a drilling rig, for recapturing drilling fluid that wouldotherwise be lost to the drill cuttings. They are a highly effectivemechanism for bulk liquids recovery and very inexpensive when comparedto other conventional forms of solids control, like that of centrifugesfor example. While all shale shakers operate on the same basicprincipal, they do come in a variety of models, which offer differinggravitational forces, coarse to very fine screen sizes, differingvibratory motions, and as few as one screen, or as many as four, on oneor more screen bed elevations.

Shale shakers apply force, usually measured in terms of gravitationalforces, ranging between four to eight times greater than earth'sgravity. The principals behind a vibratory screen is to create a bedwhere the solids and liquids phase “bounce”, causing the liquids phaseto yield under the stresses of the gravity and shaker forces. The yieldpoint is the point where the Bingham Plastic liquids phase transitionsfrom behaving like a solid, to acting as a liquid. Acting as a liquidprovides an opportunity for the liquids phase to be thrown from thesolids phase, and drop through the low micron screen of the vibratorybed. The liquids phase can then be returned directly to a processingtank, or be collected in an attached hopper or hose, and redirected toanother process such as that of centrifuges, hydro cyclones, ormembranes, for further fluids rehabilitation. Additional fluidsrehabilitation is required because conventional shale shakers are a goodmechanism to remove a substantial amount of liquids from the solids.However, this fluid typically contains small micron, high or low gravitysolids that would otherwise travel through the porosity of the vibratoryscreen, rather than be caught on the upper side of the screen with thelarger solids. Typically, shale shakers are only effective at obtaininga drill cuttings dryness of 10% to 25% by weight.

Centripetal cuttings dryers are sometimes employed to recover moredrilling mud than a drilling rig shale shaker is capable of. Cuttingsdryers can include vertical cuttings dryers or enhanced decantercentrifuges and are generally capable of producing a cuttings dryness of5% to 25% by weight. However, the liquids phase recovered in a cuttingsdryer is typically in need of substantial fluids rehabilitation.Regardless of the mechanical separation method employed, for example ashale shaker or cuttings dryer, the accepted and effective method of lowgravity solids reductions from the drilling mud is to employ ahorizontal decanter centrifuge.

Horizontal decanter centrifuges are commonly used to remove the greaterthan 5 micron size solids that otherwise pass through the shale shakerscreens. A typical drill site decanter can exert gravitational forces inexcess of 1000 times that of Earth's gravity, and as much as 3000 timesEarth's gravity force. These forces are capable of removing substantialvolumes of low gravity solids, also known as drilled solids, before thelow micron/low gravity solids volume can accumulate and becomeproblematic to the drilling operation. Decanters have many designs andoperating parameters including shorter or longer beach lengths forexample, or shallow or deeper weir settings to facilitate longer fluidsretention or a dryer solids discharge. It is up to the designers andoperators of the decanter to balance the operating parameters againstthe specific needs of the drill site.

As drilling mud is fed into a rotating horizontal decanter-typecentrifuge, the centripetal forces exerted by the rotating bowl on thewet cuttings force them to the inside surface of the bowl. Thecentripetal force on the cuttings increases with the rotational speed ofthe bowl. At sufficient rotational speed, the centripetal forces on thecuttings will be high enough to overcome the yield strength of the fluidand the large solids will tend to shed fluid at a rate that is slowed bythe viscosity of the fluid. If the rotational acceleration of the bowlis not fast enough, the centripetal force on the smallest solid particlewithin the drilling mud will not be high enough to break the yieldstrength of the drilling fluid and the low micron solids will remain inthe fluid regardless of how long the fluid remains in the decanter. Butif the rotational acceleration of the bowl is high enough to apply asufficient centripetal force on the smallest solids within the drillingmud for it to break the yield strength of the fluid, the smallest solidswill sink within the fluids. The rate they sink at is governed byStokes' law which predicts that a particle will sink (or float) andaccelerate up to the speed (terminal velocity) where the exerted forcescausing the particle to move are equal to the viscous (or drag) forcesthat oppose the motion.

Residual drilling fluid or water on the drill cuttings waste isconsidered contamination and must be managed according to local orfederal regulations. As illustrated in FIG. 1, the drill cuttings (fromthe shale shaker or other solids control equipment (108)) and lowgravity solids underflow (102) (from the onsite decanter) are typicallycollected at the drill site in an onsite unstabilized drill cuttingsmanagement systems such as a three or four sided bins (103) and mixedwith a stabilizing agent, for example sawdust or liquids absorbingpellets, to absorb the free leachable fluids and the stabilizationmaterial delivered to and stored at the site (104). The mix off istypically done by means of a wheeled loader or track excavator (105).The stabilized drill cuttings waste can then be transported safely usingconventional transport methods, such as sealed end dump trailers. Thestabilized drill cuttings waste is stored (109) and transported tospecially designed landfills (106) featuring leachate collection systemsand impervious liners. Landfills are built for long term storage. Makeupbase oil or OBM is transported to the site (107) to cover the OBM lossesresulting from the mix off process. The OBM is stored at the site (110)for use in the active mud system (111) for the drilling rig (112).

From left to right, FIG. 2 is offered to demonstrate the OBMcontaminated drill cuttings waste in a natural state (201), posttreatment of a drilling rig shale shaker. The center picture (202) isthat of a stabilizing (or bulking) agent, and picture on the right (203)shows the stabilized drill cuttings (ready for storage in a landfill).

Efforts to recover OBM drilling fluid from drill cuttings waste arecontinually being researched in an effort to find a process thatbalances clean drill cuttings waste with a processing cost less than orequal to the cost of the OBM drilling fluid. The quality of therecovered OBM (or base oil) is also an important consideration, if notcritical to re-marketing efforts.

For example, U.S. Pat. No. 5,090,498 describes an onsite process whereinwater or oil is used as a wash medium to wash the oil contaminated drillcuttings in a series of washing tanks. As the solids phase separates inthe wash tanks, a pump conveys the slurry from each wash tank to acentrifuge for maximum liquids phase removal. The “cleaned” drillcuttings are then moved to a low temperature thermal processor whichoperates at a temperature setting of less than 200° C., in accordancewith offshore drilling regulations. The process itself is complex andnot well suited for tight shale drilling of the 21^(st) century. Tightshale's are essentially compacted clays and by drilling the shale andtransporting it up the wellbore, while removing the pressure of theearth causes substantial particle degradation. Essentially the clayshave a seemingly infinite surface area, making separation ofhydrocarbons and low gravity solids in a wash medium uneconomical, dueto the particle settling velocity. Such is further exacerbated by thepresence of water as the wash medium. Clays are naturally hydrophilicand the presence of water as the wash medium causes the clays to swellthrough the absorption of more water, decreasing the bulk density of thesolids phase.

U.S. Pat. No. 4,139,462 describes an onsite process wherein as the oilcontaminated drill cuttings waste is passed over a conventional rigshale shaker, the drill cuttings are subjected to a low pressure dieselwash process to remove excess oil base mud from the drill cuttings. Therig shale shaker is effectively equipped with a low-tech spray bar tofacilitate a wash process as the drill cuttings travel over thevibratory screen deck. A centripetal solids separation process couldalso be used to further reduce the volume of liquids on the drillcuttings, prior to a thermal process being employed to remove theresidual hydrocarbons still remaining on the drill cuttings. The thermalprocess must be performed within an inert atmosphere because of thepossibility of fire or explosion. While the embodiment is likely toachieve high, if not complete separation of the hydrocarbons from thedrill cuttings waste, the process is very inefficient when compared tomore modem Low Temperature Thermal processors and does not reflectmodern health and safety standards. For example, the use of diesel fuelas a drilling fluid has been banned by some regulatory bodies, due tovolatiles that are often present in diesel fuel. The use of a dieselspray bar would cause additional volatiles to become airborne around theshale shaker area, due to the vibratory action of the screen deck whichis in an area frequented by workers and likely to cause a significanthealth or safety risk. The embodiment is also unpractical because tocentrifuge drilling mud at an ambient temperature of 25° C., theviscosity of a recovered oil base liquids phase would be at or near 2.5centistokes, which is not sufficiently low enough to achieve asignificant liquids phase reduction from the solids phase. Thus, thethermal process would still be required to remove most of the liquidsphase.

Another example of an oil recovery process is called an Oil RecoveryUnit (ORU) and described in U.S. Pat. Nos. 8,287,441 and 8,668,634.These patents detail a process where unstabilized OBM drill cuttings arecollected from a conventional shale shaker and conveyed into ahorizontal decanter centrifuge. Specifically, an auger delivers the“wet” drill cuttings into the horizontal decanter that is designed toaccept heavy, (greater than 50%) solids laden material. The materialspills from the auger delivery system and falls into the big bowldecanter which is spinning at such a rate that the drill cuttings aresubjected to substantial centripetal forces, for example, 1,000 to 2,000g-forces. This force causes the heavier solids to settle along the innerwall of the bowl while the liquids phase leaches into the pond sectionof the horizontal decanter. The solids phase is conveyed to the conicalend where it moves up the beach of the centrifuge and is ejected fromthe bowl section via wear resistant ports. The technology is at leastpartially effective at removing free liquids on drill cuttings waste,generally achieving a residual liquids of 20% to 50% (by volume), and aslow as 10% residual liquids (by volume). The liquids phase flows in theopposite direction from which the solids are conveyed, and is collectedat the opposite end of the bowl where the liquids phase spills over theweirs of the bowl section. This method of separating the liquids phaseand solids phase is unique in that the bowl allows for both asignificant removal of the OBM drilling fluid from the drill cuttingsand could also achieve a simultaneous reduction of low gravity solidsfrom the liquids phase, which can be as little as approximately 5%solids (by volume).

While the Oil Recovery Unit is capable of reclaiming more oil base mudthan conventional shale shakers alone, it has several drawbacksincluding:

1) The equipment described is very expensive and require one or moreonsite operators be present to monitor the equipment when in operation.Given that a drilling rig typically only uses OBM for two weeks of atypical four week well, means that the technology can only be utilizedfor 50% of the time, while sitting idle the other 50% of the time.

2) For the equipment described to function at its greatest potential,additional heat energy is required, to alter the viscosity of theliquids phase, which is contaminating the drill cuttings. Ideally, theprocess should maintain a minimum feed temperature of approximately 50°C., which means additional power must be used for the process tofunction at its greatest potential. Given drilling rigs are alwaysoperating in remote areas and otherwise do not have access to gridelectricity, diesel powered generators must typically be used to supplythe required electric energy. To quantify the significance of the heatenergy input, one must consider the fact that it takes 1837 BTU's toraise the temperature of 1 m3 (cubic meter) of unstabilized drillcuttings containing 30% hydrocarbons (by volume) and 5% water (byvolume), by 1° C. this presumes there is no loss of heat energy due toinefficiencies in the design.

3) As mentioned, the technology can reclaim more oil base mud thanconventional shale shakers, but the drill cuttings still containresidual liquids of approximately 20% to 50% (by volume), and as low as10% residual liquids (by volume). Given the residual contamination isstill high enough to emit a distinct odor of hydrocarbons, and theresidual contamination is still visually obvious, the marketability ofsuch a technology as ‘environmentally advantageous’ is extremelylimited.

4) Issues also exist relating to gearbox sizing. Generally, decantercentrifuges are designed to process a slurry with a solids phase of lessthan 20% (by volume). Dewatering a heavy solids phase is limited bytorque in the gear box and subsequently, the technology described inU.S. Pat. No. 8,287,441 and U.S. Pat. No. 8,668,634 is unable to keep upwith fast hole drilling where greater than five cubic meters of oilbased drilling mud contaminated drill cuttings are generated each hour.

Centripetal cuttings separators which employ greater than 400gravitational forces are at least partially effective at removing freeliquids on drill cuttings waste, generally achieving a residual liquidsof 10% to 25% (by weight), and as low as 5% liquids (by weight).However, the recovered oil from a centripetal cuttings separator istypically very high in low gravity drilled solids for example,conventional centripetal cuttings separators (as described inInternational Publication Number WO 03/102359 and U.S. Pat. No.5,256,289, the disclosures of which are herein incorporated byreference) to remove up to about 50% (by volume) of the recoverablehydrocarbons and/or water content present as a liquids phase on thesolids phase would work in conjunction with another form of OBM drillcuttings treatment, effectively pre-drying the drill cuttings wasteprior to employing a secondary form of treatment (see also, for example,commonly assigned, copending U.S. patent application Ser. No.62/212,754, the disclosure of which is herein incorporated by referencein its entirety).

Thermal processors have been used to remove hydrocarbon contaminationfrom materials in the past, for example drill cuttings wastecontaminated with OBM. This technology is known to be effective, heatingthe contaminated soil material to the point where the water andhydrocarbons evaporate. The hydrocarbon material is then typicallyrecondensed using a condenser to remove the heat energy from thehydrocarbon vapor and recapture it in a vessel as a liquid, typicallymaking it also available for reuse.

Low Temperature Thermal (LTT) technology is considered to be very energyefficient (when compared to other thermal evaporators, for example)because the energy loss can be negligible. Thermtec AS manufactures anLTT processor, commonly known as a Thermomechanical Cuttings Cleaner(TCC), or Hammermill processor. The TCC processor uses a drive unit torotate a shaft with wear-resistant paddles to hammer the waste,converting kinetic energy to heat energy. The friction is created as theOBM contaminated drill cuttings waste is conveyed to the inside surfaceof the stationary outer wall of the reactor. There, high-speedwear-resistant paddles are rotating with close clearance to the reactorwall. The solids within the drill cuttings waste become caught up andbroken by the tight clearances between the high speed rotating paddlesand the reactor wall. The friction causes the drill cuttings waste tobecome heated to the point where fluids flash evaporate. The water firstvaporizes as steam (further heating the hydrocarbons), followed by thehydrocarbons, leaving the solids phase in the reactor until the solidsare ejected from the process thereafter. The vapor, comprised of water,hydrocarbons (and dust) is moved through one or more heat exchangers toextract the heat energy wherein water, hydrocarbons (and dust) arecollected. It should be noted that while LTT is a technology whichevaporates the target base oil, any and all constituents which have thesame boiling point, or a lower boiling point than the base oil, are alsoforced to vaporize and thereafter become part of the recondensed liquidsphase. As such, LTT is unable to separate undesired constituents whichcan include BTEX or volatiles containing fewer than nine carbon atomsper molecule.

While drill cuttings waste contaminated with more OBM typicallyrepresents the opportunity for more recoverable oil, which is clearlybetter from an economic standpoint, the wetter the cuttings, the slowerthe TCC processor needs to be run, and/or recovered cuttings cleanlinessis sacrificed.

Efficient and effective use of LTT technology is reduced if noteliminated altogether when large amounts of water are present in thedrill cuttings waste, or the ratio of liquids to solids phaseunexpectedly changes. For example, OBM typically has an emulsified watercomponent, however, additional water accumulations from rain orsnowfall, or pressure washers at the drill site, require additional heatenergy to remove the water phase before the oil phase can be harvestedin the LTT technology (or alternatively, the process to be operatedslower). For example, the TCC processor consumes greater than 500kilowatts of electric (or equivalent mechanical) energy, per volumetriccube of OBM contaminated drill cuttings with an approximate compositionof 70% solids, 15% water, 15% oil (by weight). Interestingly, more thantwo thirds of the energy consumption is absorbed by the liquids phasetransitioning to a vapor and typically, the water phase consumes threetimes as much energy as the oil phase. Thus, to employ a centripetalcuttings dryer as a form of pretreatment to LTT would be highlyadvantageous, from both an efficiency and economic standpoint.

Thus is the need for an improved method to clean OBM contaminated drillcuttings and reuse the oil as drilling fluid. As described herein, is toutilize high gravity centripetal separator to effectively remove atleast a portion of the free liquids including water and OBM from thedrill cuttings waste, prior to employing the use of a LTT processor, toachieve a 25%, or 50%, or 100% greater volumetric throughput of the LTTprocessor; or, lower overall power consumption by greater than 25% (on avolumetric or weight measurement of LTT feed), while not losing thebenefit of recovering a substantial portion of the hydrocarbons presentin the drill cuttings waste, or sacrificing the maximum volumetricthroughput of the LTT process. In a further description of theembodiment, the addition of heat energy to the process to moreeffectively recover liquids with a centripetal cuttings separator, orremove volatiles for a better quality recovered base oil or drillingfluid, or increase the LTT processor throughput, or lower the overallcost of power consumption by utilizing natural gas heat instead of (orin addition to) electric or mechanical energy, or increase theeffectiveness of LGS's removal within conventional stripping equipmentis also described, any of which are highly desired outcomes.

As shown in the flowchart of FIG. 3, in one typical process as describedherein, drill cuttings waste is produced by a drilling rig (301)drilling an oil or gas well with OBM while not stabilizing the drillcuttings waste with a bulking agent. The first unstabilized OBM drillcuttings waste is received at a facility and stored in at leastpartially covered tanks (302) to restrict altogether, or mitigateprecipitation from settling on the drill cuttings waste, prior to theembodiment disclosed herein being employed. The first unstabilized OBMdrill cuttings waste (301) is then processed through a high gravitycentripetal separator (303) to remove otherwise leachable free liquidsincluding hydrocarbons and/or water thereby producing a second pre-driedsolids phase (304) with substantially less liquids and a third liquidsphase (305) with less solids.

The process in the high gravity centripetal cuttings separator istypically operated to achieve a maximum dryness of the second solidsphase, as opposed to a greater liquids clarity of the third liquidsphase. It can also be run to achieve a minimum amount of solids in thethird liquids phase, as opposed to a minimum amount of liquid in thesolids phase. Generally as a rule, a drier cake or a clearer liquid canbe generated, or somewhere in between, but typically both cannot beattained. Also, as the well gets deeper, the cuttings wetness goes fromdryer (less OBM contamination on the cuttings) to wetter (more OBMcontamination on the cuttings), i.e., cuttings that travel e.g. 1000meters vertically don't get beat up while traveling up the well bore andthus, they are larger and have less surface area for OBM to contaminate.Cuttings that are traveling e.g. 4000 meters through first a horizontalportion of the well are badly degraded into fine sand sized particleswhen they reach surface, thereby having more surface area and more OBMcontamination.

A high gravity centripetal cuttings separator can include for example,an enhanced horizontal decanter centrifuge as described herein orvertical cuttings dryer either of which are acceptable, provided thetechnique employs greater than 400 gravitational forces. The highgravity centripetal separator takes a first unstabilized drill cuttingsphase and produces a second solids phase (304) containing less than 10%hydrocarbons (by weight) and a third liquids phase (305) containingLGS's, which is conveyed into a LTT processor (307) wherein thetemperature is sufficient to evaporate hydrocarbons and/or water, andthe fourth vapor phase is recondensed in a condenser (308) as a fifthliquid phase (309) and collected in separate vessel which is operativelyconnected to the LTT process. The recovered liquids phase can be soldfor reuse, or disposed of as a contaminant. The sixth solids phase (310)with substantially no liquids phase is sent to landfill disposal orstorage for reuse, or blended with the second solids phase to create aless contaminated seventh solids phase (306) and sent to landfill fordisposal or storage for reuse.

Less viscous fluids are more likely to become mobilized when evenmoderate gravitational forces (for example, greater than 100 gravityforces) are exerted on them. While not illustrated on FIG. 3, a minimumtemperature of 20° C. could be maintained with the first unstabilizedOBM drill cuttings feed prior to conveying the first feed into a highgravity centripetal separator. Such could be accomplished by applyingeven small amounts of gas fired heat energy to the storage tank (302) orrecycling heat energy from the low temperature thermal process.

Alternatively, another configuration of the embodiment describes aprocess wherein additional heat energy can be applied to the drillcuttings to remove at least a portion of water, BTEX, or other undesiredvolatiles, prior to employing the high gravity centripetal separator andLTT process, in an effort to maximize the efficiency of the LTT processthroughput and quality of recovered base oil.

Specifically, the high gravity centripetal separator is capable ofremoving a portion of the liquids phase contamination from the OBM drillcuttings. The liquids phase is held on the solids phase, or the solidsphase is held within the liquids phase, or both, and thus, recovery ofthe liquids phase is only capable when higher gravitational forces areapplied, for example, 400 gravitational forces or more. The highergravitational forces cause the (Bingham Plastic) liquids phase to yieldunder the stress of gravity and the liquids phase gains temporarymobility (it behaves more like a liquid than a solid), giving it theability to be separated from the solids phase. An alternate or enhancedmethod of reducing the viscosity of the liquids phase contaminating thesolids phase is to increase the temperature of the liquids phase. FIG. 6illustrates the effects on light oil (for example diesel fuel) viscosityas the temperature increases. To increase the temperature of theunstabilized drill cuttings feed from the ambient temperature (which canbe as cold as −40° C. in some parts of North America) to greater than100° C. (in a controlled process environment) would reduce the viscosityfrom greater than 35 to less than 1.0, which is advantageous when thedesired outcome is to separate viscous liquid from solids or solids fromviscous liquid.

FIG. 4 describes this alternate version of the embodiment wherein drillcuttings waste is produced by a drilling rig, drilling an oil or gaswell with OBM for example, while not stabilizing the drill cuttingswaste (401) with a bulking agent. The first unstabilized OBM drillcuttings waste is received at a facility and stored in at leastpartially covered tanks (402) to restrict altogether, or mitigateprecipitation from settling on the drill cuttings waste, prior to theembodiment disclosed herein being employed. The first unstabilized OBMdrill cuttings waste (401) is then conveyed into a liquid tight heatingtank (403) wherein the drill cuttings waste is exposed to a hot (greaterthan 50° C. and preferably greater than 80° C. and more preferablygreater than 100° C., but generally less than 150° C.) conveyor or oilbath so that at least a portion of the free water, BTEX and volatilesare forced to vaporize as the ninth phase (404) and exit the heatingtank (403) by means of hermetically sealed conduit (not shown) where itenters a condenser (405) and subsequently recovered as the twelfthliquids phase (406). The twelfth liquids phase can be disposed of bymeans of an injection well (not shown), mixed with the sixth solidsphase (421), or other suitable disposal method, or (in the case ofvolatile hydrocarbons) reused as fuel, or (in the case of water) atleast partially reused in oil base mud. The heat energy used in theheating tank is supplied by a process heater (407) which is typicallypowered by less expensive natural gas. The heat transfer fluid (409) ispumped to the heating tank (403) and at least a portion of the heatenergy is absorbed by the water, BTEX and undesired volatiles, whichleaves the heating tank as a vapor (404). The cooler heat transfer fluidrecirculates out of the heating tank, back (408) to the process heater(407) within a closed loop.

If in the case of a hot oil bath, the oil bath fluid should be similarin composition as that of the base oil commonly used in OBM, becausesome of the hot oil bath fluid will be conveyed out of the heating tankwith the OBM contaminated drill cuttings, and some of the OBM thatbecomes liberated by the low viscosity environment will come to be mixedwith the hot oil bath fluid. The composition of the hot oil bath willover time, come to match that of the base oil or blend of base oils,used in the OBM. Thus, oil selected for the hot oil bath fluid shouldcontain 10 to 30 carbon atoms per molecule or 10 to 25 carbon atoms permolecule, or ideally, 11 to 20 carbon atoms per molecule.

While a hot oil bath would provide an excellent heat transfer means, thedesign of the heating tank is of less concern to the embodiment, otherthan to ensure the heat transfer means has sufficient capability tomaintain the desired drill cuttings feed throughput and operationaltemperature. Thus, as an alternative design of the heating tank (403), aconveyor within a jacketed trough filled with heat transfer fluid, orholo-flite auger heated with a heat transfer fluid, can be used tofacilitate the heat transfer and cause less desired portions (such aswater, BTEX and volatiles-discussed below) of the OBM to vaporize andleave the heating tank.

As previously mentioned, the OBM or drill cuttings waste can becontaminated with naturally occurring formation fluids which can containa volatile constituents with fewer than nine carbon atoms per molecule,most importantly, BTEX. BTEX is an acronym for benzene, toluene,ethylbenzene, and xylene, all of which are known to cause adverse healtheffects to humans. Further, as demonstrated in Table 1, each of the BTEXconstituents also have moderately low (closed cup) flash points and cannegatively affect the safe working parameters of the OBM by lowering theflash point of the OBM. Some regulatory bodies require OBM to have aflash point of greater than 60° C. while some operators require theflash point to be either that imposed by regulators, or 10° C. higherthan the flow line temperature of the OBM in the active mud system,whichever is greater. Thus, to lower the flash point of the OBM bypermitting BTEX to accumulate in the active mud system would almostcertainly lower the flash point of the OBM while unduly exposing workersto hazardous volatile constituents. Interestingly, three of the fourBTEX constituents are known to form an azeotrope with water which meanswhen water is present, the constituent boils in unison with water, at alower boiling temperature than either water or itself in pure (orsubstantially pure) form.

While BTEX is known to cause adverse health concerns to humans, it'simportant to note that all low flash point volatile constituents (forexample, liquids containing five to nine carbon atoms) will have anadverse effect on the quality of the recovered oil phase by reducing theflash point and if possible, should be removed.

Thus, as the first unstabilized OBM drill cuttings waste (401) isconveyed into a liquid tight/vapor tight heating tank (403), the drillcuttings waste is exposed to a heating tank comprised of either aheating conveyor or hot oil bath (heated to a temperature of greaterthan 50° C. and generally less than 150° C.) so that both free water andBTEX are forced to vaporize and leave the heating tank (403) by means ofhermetically sealed conduit (not shown) where the vapor phase enters acondenser (405) for heat extraction and subsequent liquids (water and/orBTEX and/or volatiles containing fewer than nine carbon atoms permolecule) recovery (406). FIG. 7 illustrates the normal boiling pointranges of common distillate and synthetic base oils, commonly used asthe base fluid in OBM. As illustrated, a heating tank which is heatingthe OBM contaminated drill cuttings feed to greater than 50° C. andtypically greater than 80° C. and more typically greater than 100° C.,but generally less than 150° C. would not negatively affect the makeupof common base oils, yet would generally be sufficient to evaporateundesired constituents such as benzene (at 78° C.), the azeotrope oftoluene/water (at 83° C.), the azeotrope of ethylbenzene/water (at 93°C.), the azeotrope of xylene/water (at 93° C.), and excess water (at100° C.), and/or volatiles containing fewer than nine carbon atoms permolecule that was not intended to be a portion of the OBM.

If in the case of an oil bath heating tank, the oil contaminated drillcuttings are conveyed from the heating tank by means of an auger (notshown) along the bottom of the heating tank, as a eight feed phase ofhot OBM contaminated drill cuttings. Optionally, in an effort to ensurethe eight feed phase is predictably consistent with the ratio of liquidsto solids, a pump could remove the slurry from the heating tank anddeliver it to a secondary shale shaker (not shown) inline of the eightfeed phase, before the eight feed phase is conveyed into the centripetalcuttings separator (410). The liquids phase from the shale shaker (notshown) is returned to the heating tank in a closed loop. As previouslydiscussed, FIG. 5 illustrates the reduction in viscosity of a dieseloil, specifically the drop in viscosity when the oil exceeds 100° C. Thecentripetal cuttings dryer is setup and operated to achieve maximumliquids clarity as opposed to maximum liquids recovery. In a furtherbenefit of the embodiment, it is expected that the second solids phasewill become substantially dryer (containing less liquids phase) and thethird liquids phase weigh substantially less (containing less solids)because of the reduced viscosity of the liquids phase contaminating thedrill cuttings, due to the higher temperature of the drill cuttings feedgoing to the centripetal cuttings dryer.

Once the high gravity centripetal separator (410) has removed asubstantial portion of the otherwise leachable free liquids includinghydrocarbons and/or water thereby producing a second pre-dried solidsphase (411) with substantially less liquids and a third liquids phase(412) with less solids, the second solids phase (411) is conveyed intoan operatively connected LTT processor (413) wherein the temperature issufficient to evaporate residual hydrocarbons and/or water (if present),creating a fourth vapor phase that is recondensed in a condenser (414)as a fifth liquid phase (415) and collected in separate vessel (notshown) which is operatively connected to the LTT process (413). Therecovered fifth liquids phase can be sold for reuse as a drilling fluidor used as a source of energy. The seventh solids phase (416) withsubstantially no liquids phase is sent to landfill disposal or storagefor reuse. The third liquids phase (412) with less solids is treated bymeans of a conventional stripping process (417) which can includehorizontal decanter(s) and/or disc centrifuges and/or membranes toremove sufficient amounts of LGS's or water to make the recovered tenthOBM phase (418) suitable for reuse or, mixed with the fifth liquidsphase (415) to create a blended eleventh liquids phase (419) with asubstantially diluted LGS's phase (for example, less than 1% LGS's),suitable for reuse as a drilling fluid. The thirteenth solids phase(420) from the conventional stripping process (417) is also sent to theLTT processor (413) for liquids recovery. Not only does the embodimentimprove the efficiency and effectiveness of the LTT technology bycreating a consistency in feed material (which is not typicallyavailable on a drill site), but also by directing only solids withsubstantially lower liquids contamination than that of unstabilizeddrill cuttings (401) so that the LTT technology is not slowed by theadditional liquids contamination. Additionally, the effectiveness andefficiency of the centripetal cuttings separators in this environment isimproved as well because of the reduced viscosity of the hot OBM liquidsphase contaminating the drill cuttings, and the recovered base oil andOBM will have improved characteristics like that of new base oil becauseof water and volatile stripping in the heating tank. Further,degradation of the OBM contaminated drill cuttings caused by conveying,heating and high gravity centripetal extraction does not cause aprocessing concern for the LTT process because the drill cuttingsparticles are ultimately ground up by the mechanical operation of theTCC processor. Further, the addition of heat energy at the start of theembodiment is not lost to the process of recovering the hydrocarbonsphase because the addition of less expensive natural gas heat energymitigates the need for additional electric or mechanical kinetic-to-heatenergy in the LTT process, induced by the friction of the high speedrotating paddles.

The processes described herein stresses the importance of recovering aquality base oil or quality oil base mud for reuse. An additional (andless costly) option to the processes illustrated in FIG. 3 and FIG. 4,is illustrated in FIG. 5, demonstrating a process where the samecomponents can be reconfigured while removing the most expensive capitalcost item being, the LTT equipment. FIG. 5 illustrates that the firstunstabilized OBM drill cuttings waste (502) is received at a facilityafter being shipped from the waste generators drill site (501). Thewaste is then conveyed into a liquid tight heating tank (503) whereinthe drill cuttings waste is exposed to a hot (greater than 50° C. andpreferably greater than 80° C. and more preferably greater than 100° C.,but generally less than 150° C.) conveyor or oil bath so that (a portionof the) free water, BTEX and volatiles are forced to vaporize as theninth phase (504) and exit the heating tank (503) by means ofhermetically sealed conduit (not shown) where it enters a condenser(505) and subsequently recovered as the twelfth liquids phase (506). Thetwelfth liquids phase can be disposed of by means of an injection well(not shown), mixed with the second solids phase (511), or other suitabledisposal method, or (in the case of volatile hydrocarbons) reused asfuel, or (in the case of water) at least partially reused in oil basemud. The heat energy used in the heating tank (503) is supplied by aprocess heater (507) which is typically powered by less expensivenatural gas. The heat transfer fluid (509) is pumped to the heating tank(503) and at least a portion of the heat energy is absorbed by thewater, BTEX and undesired volatiles, which leaves the heating tank as avapor (504). The cooler heat transfer fluid recirculates out of theheating tank, back (508) to the process heater (507) within a closedloop.

The eight feed phase is conveyed into the centripetal cuttings separator(510) which is operated to achieve maximum liquids recovery as opposedto maximum liquids clarity. In a further benefit of this embodiment, itis expected that the second solids phase will become substantially dryer(containing less liquids phase) and the third liquids phase weighsubstantially less (containing less solids) because of the reducedviscosity of the liquids phase contaminating the drill cuttings, due tothe higher temperature of the drill cuttings feed going to thecentripetal cuttings dryer.

Once the high gravity centripetal separator (510) has removed asubstantial portion of the otherwise leachable free liquids includinghydrocarbons and/or water thereby producing a second pre-dried solidsphase (511) with substantially less liquids, and a third liquids phase(512) with less solids, the second solids phase (511) is sent to alandfill for final disposition, or sent to a staging area for solidsreuse. The third liquids phase (512) with less solids is treated bymeans of a conventional stripping process (517) which can includehorizontal decanter(s) and/or disc centrifuges and/or membranes toremove sufficient amounts of LGS's or water to make the recovered tenthOBM phase (518) with a substantially lower LGS's phase (for example,less than 1% LGS's), suitable for reuse as a drilling fluid, or used asa source of energy. Note also the seventh phase (516), the eleventhphase (519), and the thirteenth phase (520) also demonstrated in thefigure.

While the condenser (308, 405, 414 or 505) described herein wouldtypically consist of a fin-fan or radiator to displace the heat energyof the vapor phase, the condenser can consist of a shell and tube orplate and frame or other suitable heat exchanger, capable of recoveringthe lost heat from the condenser and reusing it within the process ofheating the drilling waste storage tank (302 or 402 or 502), or in-lineof the return line (408 or 508) from the heating tank, or supplementalheat to what is also provided by the process heater (407 or 507).

As described herein, these problems and others in this area areaddressed with the invention described herein. Thus, the scope of theinvention shall include all modifications and variations that may fallwithin the scope of the attached claims. Other embodiments of theinvention will be apparent to those skilled in the art fromconsideration of the specification and practice of the inventiondisclosed herein. It is intended that the specification and examples beconsidered as exemplary only, with a true scope and spirit of theinvention being indicated by the following claims.

What is claimed is:
 1. A process for removing hydrocarbon and watercontamination from a first phase oil base mud contaminated drillcuttings containing liquids and solids, and recovering liquids in amulti-stage separation process, comprising placing the first phase oilbase mud contaminated drill cuttings in a container and managing theflow of the first phase oil base mud contaminated drill cuttings intoand out of the container to a substantially consistent ratio of liquidsphase to solids phase; conveying the first phase oil base mud drillcuttings into a high gravity centripetal cuttings separator to create asecond solids phase with less water and hydrocarbon contamination and athird liquids phase with an approximately equal ratio of liquids tosolids; conveying the said third liquids phase with an approximatelyequal ratio of liquids to solids into a low temperature thermal processutilizing stationary reactor walls and high speed rotating paddles, thesolids in the third phase causing friction between the stationaryreactor walls and high speed rotating paddles of the low temperaturethermal process, and the friction generating heat energy causingevaporation of the liquids portion of the third phase into a fourthvapor phase and a sixth solids phase; condensing the fourth vapor phaseinto a fifth liquid phase comprising water and/or hydrocarbons, andcollecting the fifth liquid phase; and, mixing the sixth solids phasewith the second solids phase to form a seventh mixed solids phase;resulting in enhanced liquids and solids recovery.
 2. The process ofclaim 1 wherein the high gravity centripetal cuttings separator exertsgreater than 400 gravitational forces on the oil base mud contaminateddrill cuttings waste.
 3. The process of claim 1 wherein the high gravitycentripetal cuttings separator exerts greater than 1000 gravitationalforces on the oil base mud contaminated drill cuttings waste.
 4. Theprocess of claim 1 wherein the high gravity centripetal cuttingsseparator is operated to obtain maximum dryness of the second solidsphase.
 5. The process of claim 1 wherein the first phase oil base mudcontaminated drill cuttings is heated to a temperature of at least 20°C. at 0 PSIG.
 6. The process of claim 5 wherein the heating is providedby natural gas or recycled heat energy from the condensing of the fourthvapor phase.
 7. The process of claim 1 wherein the centripetal cuttingsseparator removes greater than 50% by volume of the liquids phase fromthe first oil base mud contaminated drill cuttings phase.
 8. The processof claim 7 wherein the liquids phase comprises at least free water,hydrocarbons, and/or emulsified water.
 9. The process of claim 1 whereinthe enhanced liquids and solids recovery includes an increase of drillcuttings waste throughput of the low temperature thermal process bygreater than 25% and/or cleaner solids recovery.
 10. The process ofclaim 1 wherein the enhanced liquids and solids recovery includes anincrease of drill cuttings waste throughput of the low temperaturethermal process by greater than 50% and/or cleaner solids containingless hydrocarbon contamination.
 11. The process of claim 1 wherein theenhanced liquids and solids recovery includes an increase of drillcuttings waste throughput of the low temperature thermal process by upto 100% and/or cleaner solids recovery.
 12. A process for removinghydrocarbons and water from a first phase oil base mud contaminateddrill cuttings and recovering liquids in a multi-stage separationprocess, comprising: heating the first phase oil base mud contaminateddrill cuttings to remove at least a portion of undesired liquidconstituents as a ninth vapor phase, and recondensing the ninth vaporphase in an operatively connected condenser thereby forming a twelfthliquids phase, and forming a heated eight phase oil base mudcontaminated drill cuttings containing a liquids portion and a solidsportion; conveying the heated eight phase of oil base mud contaminateddrill cuttings into a high gravity centripetal cuttings separator tocreate a second solids phase containing less water and hydrocarbonscontamination than the eight phase, and a third liquids phase with lesssolids than the eight phase; conveying the third liquids phase to afluid stripping process removing low gravity solids, producing athirteenth phase of low gravity solids with reduced liquids and a tenthliquids phase with substantially no solids; conveying the second solidsphase and thirteenth low gravity solids phase to a low temperaturethermal process utilizing stationary reactor walls and high speedrotating paddles, the interaction between the solids of the second andthirteenth phase and the stationary reactor walls and high speedrotating paddles generating at least a portion of the heat energynecessary to cause evaporation of the liquids of the second andthirteenth phase into a fourth vapor phase; condensing the fourth vaporphase into a fifth liquid phase comprising water and/or hydrocarbons,and collecting the fifth liquid phase; and, collecting the tenth liquidsphase from the fluid stripping process which is optionally stored in astorage tank, or mixed with the fifth liquids phase to create a eleventhliquids phase, for use in an oil base mud drilling fluid; resulting inenhanced liquids and solids recovery.
 13. The process of claim 12wherein the ninth phase of undesired liquid constituents removedcomprise at least a portion of water, and/or at least a portion ofbenzene, and/or at least a portion of toluene, and/or at least a portionof ethylbenzene, and/or at least a portion of xylene from the firstphase.
 14. The process of claim 12 wherein the undesired liquidconstituents removed include liquids with a closed cup flash point ofless than 60° C.
 15. The process of claim 12 wherein the undesiredliquid constituent removed includes a gas or liquid containing fewerthan nine carbon atoms per molecule.
 16. The process of claim 12 whereinthe viscosity of the liquids portion of the eight phase is less than 1.0cP (centipoise) as a result of the said heating.
 17. The process ofclaim 12 wherein the viscosity of the liquids portion of the eight phaseis less than 0.75 cP as a result of the said heating.
 18. The process ofclaim 12 wherein the high gravity centripetal cuttings separator exertsgreater than 400 gravitational forces on the oil base mud contaminateddrill cuttings.
 19. The process of claim 12 wherein the high gravitycentripetal cuttings separator exerts greater than 1000 gravitationalforces on the oil base mud contaminated drill cuttings.
 20. The processof claim 12 wherein the high gravity centripetal cuttings separator isoperated to achieve a minimum amount of solids in the third liquidsphase.
 21. The process of claim 12 wherein the heating of the firstphase of oil base mud contaminated drill cuttings includes the use of aholo-flight heating screw.
 22. The process of claim 12 wherein theheating of the first phase of oil base mud contaminated drill cuttingsincludes the use of a conveyor within a jacketed heating trough.
 23. Theprocess of claim 12 wherein the heating of the first phase of oil basemud contaminated drill cuttings includes the use of a tank filled withhot oil containing 10 to 30 carbon atoms per molecule.
 24. The processof claim 12 wherein the heating of the first phase of oil base mudcontaminated drill cuttings includes the use of a tank filled with hotoil containing 10 to 25 carbon atoms per molecule.
 25. The process ofclaim 12 wherein the heating of the first phase of oil base mudcontaminated drill cuttings includes the use of a tank filled with hotoil containing 11 to 20 carbon atoms per molecule.
 26. The process ofclaim 12 wherein the enhanced liquids and solids recovery includes anincrease of drill cuttings waste throughput of the low temperaturethermal process by greater than 25% and/or cleaner solids recovery. 27.The process of claim 12 wherein the enhanced liquids and solids recoveryincludes an increase of drill cuttings waste throughput of the lowtemperature thermal process by greater than 50% and/or cleaner solidsrecovery.
 28. The process of claim 12 wherein the enhanced liquids andsolids recovery includes an increase of drill cuttings waste throughputof the low temperature thermal process by up to 100% and/or cleanersolids recovery.
 29. The process of claim 12 wherein the heating of thefirst phase of oil base mud contaminated drill cuttings is provided bynatural gas and/or recycled heat energy from the low temperature thermalprocess.
 30. A method of treating a first phase oil base mudcontaminated drill cuttings phase by, heating the first phase oil basemud contaminated drill cuttings in a heating tank and causingconstituents with a lower boiling point than the boiling points of thebase oil portion of the oil base mud, to at least partially vaporize andleave the vapor tight heating tank as a ninth vapor phase wherein, thevapors are recondensed in an operatively connected condenser andcollected as a separate twelfth liquids phase, and further processingthe eight phase of oil base mud contaminated drill cuttings phase in acentripetal cuttings separator to create a liquids phase containing lesssolids than the first phase oil base mud contaminated drill cuttings,and a solids phase containing less liquids than the first phase oil basemud contaminated drill cuttings, resulting in an enhanced recoveredliquids phase which is at least partially void of water, benzene,toluene, ethylbenzene and xylene and constituents containing fewer thannine carbon atoms per molecule.